Pyrite Formation Sedimentary
In situ characterization of pyrite from multiple
The sulfur isotopic composition and trace element content recorded in sedimentary pyrite have been widely used as a proxy to establish the geochemistry of pyrite-forming fluids.
Sedimentary pyrite sulfur isotopes track the local …
To explore the importance of local vs. global sulfur-cycle controls on variations in pyrite sulfur isotopes, the authors couple carbon-nitrogen-sulfur concentrations and stable isotopes of ...
Mechanisms of sedimentary pyrite formation
Experiments with in vitro cultures demonstrate the role of cell walls in directing and promoting the precipitation process. Synthesis of nanoscale pyrite, trace element …
(PDF) Sedimentary Pyrite Formation in a Seasonally
Sedimentary pyrite records are essential for reconstructing paleoenvironmental conditions, but these records may be affected by seasonal fluctuations in oxygen concentration and temperature, which ...
Sedimentary pyrite formation: An update
Sedimentary pyrite formation during early diagenesis is a major process for controlling the oxygen level of the atmosphere and the sulfate concentration in seawater over geologic time.
(PDF) Introduction to pyrite
On the basis of different P-T regime and mode of formation, mineral genesis has been grouped under igneous, sedimentary and metamorphic processes. Various aspects of these processes are explained ...
(PDF) Sedimentary pyrite as a trap of organic matter: …
This formation is enriched in pyrite present in abundance in the forms of framboids, polyframboids and other concretions of a relatively large size for sedimentary pyrite (a few tens to hundreds ...
(PDF) Formation pathways of Precambrian sedimentary …
A bimodal distribution of positive versus negative δ 56 Fe values can be attributed to two different processes of pyrite formation, Fe (oxyhydr)oxide sulfidation, …
Abiotic Pyrite Formation Produces a Large Fe Isotope
The iron isotope composition of sedimentary pyrite has been proposed as a potential proxy to trace microbial metabolism and the redox evolution of the oceans. We demonstrate that Fe isotope fractio...
The Morphological Characteristics of Authigenic Pyrite …
Pyrites are widely distributed in marine sediments, the morphology of which is applied as a proxy to infer the redox conditions of bottom water, and identify diagenetic stages and hydrocarbon leakage activities. In this review, the methods used for the morphological study of pyrite are summarized. The textural and size characteristics of …
Invisible Gold in Pyrite from Epithermal, Banded-Iron-Formation-Hosted
In the latter case, the rim of a grain may be composed of precipitation from a fluid while the core is of sedimentary origin. These suggest a hydrothermal influence on pyrite formation in the South Deep deposit. The rounded pyrite is sedimentary in origin, and the angular pyrite is thought to have precipitated from hydrothermal fluids.
Sedimentary pyrite formation in the Arabian Sea
Conversely, in euxinic environments pyrite formation already commences in the water column (syngenetic pyrite). This results in relatively low sedimentary C/S ratios, and a positive S intercept in a S versus C plot. In this study, sulphate reduction and pyrite formation were investigated in sediment records from the northern Arabian Sea.
The formation of low-temperature sedimentary pyrite and …
This contribution is an updated review on sedimentary pyrite and on its role in well-consolidated research topics, such as the biogeochemical cycles and the studies on sediment-hosted ore deposit studies, as well as new frontiers of research, such as astrobiology. Textural and compositional information preserved in sedimentary pyrite …
Pyrite formation from FeS and H
The exergonic reaction of FeS with H 2 S to form FeS 2 (pyrite) and H 2 was postulated to have operated as an early form of energy metabolism on primordial Earth. Since the Archean, sedimentary pyrite formation has played a major role in the global iron and sulfur cycles, with direct impact on the redox chemistry of the atmosphere.
(PDF) Formation pathways of Precambrian sedimentary pyrite…
Iron isotope compositions (expressed as δ 56 Fe) in sedimentary pyrite have been widely used as tracers of redox and chemical evolution of the ocean through geological time.
The formation of low-temperature sedimentary pyrite and its …
Textural and compositional information preserved in sedimentary pyrite from sediment-hosted ore deposits has contributed to elucidate their environment of forzmation.
Pyrite mega-analysis reveals modes of anoxia through …
Sedimentary pyrite formation occurs via reaction between reduced Fe and S, a process that is typically catalyzed in the marine environment during degradation of …
Sulfide minerals in sediments | SpringerLink
Pyrite formation in sediments is thought to be limited either by the microbial production of sulfide (organic carbon or sulfate limitation) or by the availability of reactive iron minerals (iron limitation).
Pyrite Mineral | Uses and Properties
The conditions of pyrite formation in the sedimentary environment include a supply of iron, a supply of sulfur, and an oxygen-poor environment. This often occurs in association with decaying organic materials.
Sedimentary pyrite δ34S differs from porewater sulfide
A fundamental control on the sedimentary sulfur cycle is the rate of microbial sulfate reduction (MSR), which generates the reduced sulfur required for organic S and pyrite formation as well as sulfide-oxidizing metabolisms.
Deconvolving microbial and environmental controls on marine sedimentary …
The sedimentary pyrite sulfur isotope record is a robust archive of past biogeochemical cycling, yet considerable uncertainty remains about how to interpret it because it is a complex mixture of biological and environmental forcings and can be influenced at multiple stages of mineral precipitation during and after deposition.
Sedimentary pyrite formation: An update
Sedimentary pyrite formation during early diagenesis is a major process for controlling the oxygen level of the atmosphere and the sulfate concentration in seawater over geologic time. The amount of pyrite that may form in a sediment is limited by the rates of supply of decomposable organic matter, dissolved sulfate, and reactive detrital iron minerals. …
Variability of sedimentary pyrite δ34S records: A case study …
Studies on sedimentary pyrite revealed that syngenetic framboids are commonly smaller and exhibit limited size variation (∼3–7 μm, e.g., Wilkin et al., 1996; ... As a result, it is crucial to consider factors such as the stage of biological pyrite formation and the basin isolation effect before interpreting the variability of bulk ...
The formation mechanisms of sedimentary pyrite nodules determined by
Abstract. Redox sensitive trace elements in pyrite, including nodules, are increasingly used to infer the chemical conditions of ancient oceans—but considerable uncertainty remains regarding the mechanism and timing of nodule formation.
Sedimentary Pyrite Formation in a Seasonally …
Formation of the iron sulfide mineral pyrite in sediments has contributed to long-term oxygen accumulation on Earth, and pyrite's sulfur isotope composition in …
Sedimentary parameters control the sulfur isotope …
The sulfur isotope composition of pyrite found in marine sediments and sedimentary rocks is often used to try to reconstruct the coupled cycles of carbon, …
Frontiers | Mechanisms of Pyrite Formation Promoted by Sulfate-Reducing
Because sulfides are mainly produced by sulfate-reducing bacteria (SRB) in modern sedimentary environments, microorganisms are assumed to drive the formation of iron sulfides, in particular, pyrite. However, the exact role played by microorganisms in pyrite formation remains unclear and, to date, the precipitation of pyrite in microbial ...
Authigenic pyrite formation and re-oxidation as an …
The results were then combined with the pyrite morphologies (pyrite textures and the size distributions of framboidal pyrite) to characterize the sedimentary environment and to examine the process of pyrite formation and …
Mechanisms of sedimentary pyrite formation | Request PDF
Request PDF | Mechanisms of sedimentary pyrite formation | The mechanisms of pyrite formation are reviewed. Advances since 1994 in our understanding of the mechanisms and rate of pyrite formation ...
Sedimentary pyrite proxy for atmospheric oxygen: …
The reason for this important step is that later fluid processes and metamorphism acting on the shale, may cause recrystallisation and/or pyrite overgrowths on the original sedimentary pyrite (Fig. 1), and consequently change the composition of the pyrite aggregate for analysis or introduce new non-sedimentary pyrite.
Transient marine euxinia at the end of the terminal Cryogenian
Here, we report the occurrence of abundant pyrite concretions from the topmost Nantuo Formation 5,23,24, a sedimentary sequence deposited during the terminal Cryogenian Marinoan glaciation in the ...
Isotopically "heavy" pyrite in marine sediments due to high
Using a diagenetic model, we show that the amount of pyrite formed at the sediment-water interface has increased over the past few centuries in response to …
Sedimentary pyrite formation in the Arabian Sea
Sediment records from the Arabian Sea thus provide an excellent opportunity to study the pathways of sedimentary pyrite formation under di¡erent palaeoenvironmental conditions, which can be used to reconstruct past variations in OMZ intensity. 2. Materials and methods During the Netherlands Indian Ocean Programme (NIOP) in 1992, piston cores ...
Trace element content of sedimentary pyrite as a new …
Sedimentary pyrite formed in the water column, or during diagenesis in organic muds, provides an accessible proxy for seawater chemistry in the marine…
Mechanisms and rates of pyrite formation from
Mechanisms and rates of pyrite formation from hydrothermal fluid revealed by iron isotopes. Author links open overlay panel Gleb S. Pokrovski, Marc Blanchard, Gaëlle Saunier, Franck Poitrasson. ... (and also sedimentary) environments may reflect a variety of factors related to the source of rocks and fluids, temperature (T), ...
Pyrite morphological evidence for sedimentary conditions …
Compared with previous studies on pyrite evidence for sedimentary conditions of the Wufeng Formation and the Longmaxi Formation, this research further enriched the relatively few shale pyrite research data in the study area, and established the correlation between pyrite evidence and high-quality shale reservoir development …
Trace element evidence for diverse origins of superheavy pyrite …
Sedimentary pyrite formation is driven by microbial sulfate reduction where microorganisms use dissolved sulfate as a terminal electron acceptor to oxidize organic matter, producing sulfide (Berner, 1970). This sulfide then goes on to react with iron to eventually form pyrite.
The formation mechanisms of sedimentary pyrite nodules determined …
Redox sensitive trace elements in pyrite, including nodules, are increasingly used to infer the chemical conditions of ancient oceans—but considerable uncertainty remains regarding the mechanism and timing of nodule formation.